Sodium ion → 7,8-Dimethoxy-5-formyl-2H-1-benzopyran

HRID 2327682Notes

Reaction equation

HRID 2327682 reaction equation
[CH2:33]1[NH:34][CH2:35][CH2:36][O:37][CH2:38]1.[CH3:1][O:2][c:3]1[c:4]([O:17][CH3:18])[c:5]2[c:6]([c:11]([C:13](=[O:14])[O:15][CH3:16])[cH:12]1)[CH:7]=[CH:8][CH2:9][O:10]2.[CH3:20][O:21][CH2:22][CH2:23][O:24][Al+:25][O:26][CH2:27][CH2:28][O:29][CH3:30].[CH3:41][c:42]1[cH:43][cH:44][cH:45][cH:46][cH:47]1.[H-:19].[H-:32].[Na+:31].[Na+:40].[OH-:39]>>[CH3:1][O:2][c:3]1[c:4]([O:17][CH3:18])[c:5]2[c:6]([c:11]([CH:13]=[O:14])[cH:12]1)[CH:7]=[CH:8][CH2:9][O:10]2

Participants

8

Reactant 7

HCID 923Sodium ion2×HCID 961HydroxideHCID 1140TolueneHCID 8083MorpholineHCID 166653Hydride2×HCID 12849831Methyl 7,8-dimethoxy-2H-1-benzopyran-5-carboxylateHCID 18764105Bis(2-methoxyethoxy)alumanylium

Product 1

HCID 128498327,8-Dimethoxy-5-formyl-2H-1-benzopyran

Sources & evidence

ORD record
ord-e45825af1df147358e2f58058f09989b
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (10/10)

Reaction notes

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