Acetate → 4-Carbomethoxy-3'-Acetylbiphenyl

HRID 2327832Notes

Reaction equation

HRID 2327832 reaction equation
[C:1]([P:2]([C:3]([CH3:4])([CH3:5])[CH3:6])[c:7]1[cH:8][cH:9][cH:10][cH:11][c:12]1-[c:13]1[cH:14][cH:15][cH:16][cH:17][cH:18]1)([CH3:19])([CH3:20])[CH3:21].[C:22]([CH3:23])(=[O:24])[c:25]1[cH:26][c:27]([B:31]([OH:32])[OH:33])[cH:28][cH:29][cH:30]1.[C:47]([O-:48])(=[O:49])[CH3:50].[C:52]([O-:53])(=[O:54])[CH3:55].[CH3:36][O:37][C:38]([c:39]1[cH:40][cH:41][c:42]([Cl:45])[cH:43][cH:44]1)=[O:46].[F-:34].[K+:35].[Pd+2:51]>>[C:22]([CH3:23])(=[O:24])[c:25]1[cH:26][c:27](-[c:42]2[cH:41][cH:40][c:39]([C:38]([O:37][CH3:36])=[O:46])[cH:44][cH:43]2)[cH:28][cH:29][cH:30]1

Participants

8

Reactant 7

HCID 175Acetate2×HCID 813Potassium CationHCID 14307Methyl 4-chlorobenzoateHCID 28179Fluoride IonHCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)HCID 27342152-(Di-tert-butylphosphino)biphenylHCID 27343103-Acetylphenylboronic acid

Product 1

HCID 43288044-Carbomethoxy-3'-Acetylbiphenyl

Sources & evidence

ORD record
ord-721ec674624a42dcba2bd8328625e901
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (10/10)

Reaction notes

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