Azido(trimethyl)stannane → HCID 178477874, compound

HRID 232851Notes

Reaction equation

HRID 232851 reaction equation
[Cl:1][C:2]1[CH:11]=[C:10]2[C:5]([CH:6]=[CH:7][C:8]([CH2:12][O:13][C:14]3[CH:33]=[CH:32][C:17]4[O:18][CH2:19][C:20]5[CH:31]=[CH:30][CH:29]=[CH:28][C:21]=5[CH:22]([O:23][CH2:24][CH2:25][C:26]#[N:27])[C:16]=4[CH:15]=3)=[N:9]2)=[CH:4][CH:3]=1.C[Sn]([N:38]=[N+:39]=[N-:40])(C)C>>[Cl:1][C:2]1[CH:11]=[C:10]2[C:5]([CH:6]=[CH:7][C:8]([CH2:12][O:13][C:14]3[CH:33]=[CH:32][C:17]4[O:18][CH2:19][C:20]5[CH:31]=[CH:30][CH:29]=[CH:28][C:21]=5[CH:22]([O:23][CH2:24][CH2:25][C:26]5[NH:40][N:39]=[N:38][N:27]=5)[C:16]=4[CH:15]=3)=[N:9]2)=[CH:4][CH:3]=1

Participants

3

Reactant 2

HCID 5104973Azido(trimethyl)stannaneHCID 233592112-(7-Chloroquinolin-2-yl)methoxy-11-(2-cyanoethoxy)-6,11-dihydrodibenz[b,e]oxepine

Product 1

HCID 178477874HCID 178477874, compound

Procedure

2-(7-Chloroquinolin-2-yl)methoxy-11-(2-cyanoethoxy)-6,11-dihydrodibenz[b,e]oxepine and trimethyltin azide were used and reacted in the same manner as in Example 30 to obtain the title compound.

Workup

  1. customreacted in the same manner as in Example 30

Sources & evidence

ORD record
ord-28ccbcf369f34e55b7b8717235ce75ae
Source dataset
uspto-grants-1997_01
Patent number
US05591752

Reaction notes

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