Ammonium Chloride → HCID 178419899, compound

HRID 232853Notes

Reaction equation

HRID 232853 reaction equation
[C:1]([CH2:3][S:4][CH:5]1[C:11]2[CH:12]=[CH:13][CH:14]=[CH:15][C:10]=2[CH2:9][O:8][C:7]2[CH:16]=[CH:17][C:18]([O:20][CH2:21][C:22]3[CH:31]=[CH:30][C:29]4[C:24](=[CH:25][CH:26]=[CH:27][CH:28]=4)[N:23]=3)=[CH:19][C:6]1=2)#[N:2].[Cl-].[NH4+].[N-:34]=[N+:35]=[N-:36].[Na+]>>[N:23]1[C:24]2[C:29](=[CH:28][CH:27]=[CH:26][CH:25]=2)[CH:30]=[CH:31][C:22]=1[CH2:21][O:20][C:18]1[CH:17]=[CH:16][C:7]2[O:8][CH2:9][C:10]3[CH:15]=[CH:14][CH:13]=[CH:12][C:11]=3[CH:5]([S:4][CH2:3][C:1]3[NH:36][N:35]=[N:34][N:2]=3)[C:6]=2[CH:19]=1

Participants

4

Reactant 3

HCID 25517Ammonium ChlorideHCID 33557Sodium AzideHCID 2335915911-Cyanomethylthio-2-(quinolin-2-yl)methoxy-6,11-dihydrodibenz[b,e]oxepine

Product 1

HCID 178419899HCID 178419899, compound

Procedure

11-Cyanomethylthio-2-(quinolin-2-yl)methoxy-6,11-dihydrodibenz[b,e]oxepine, ammonium chloride and sodium azide were used and reacted in the same manner as in Example 32 to obtain the title compound.

Workup

  1. customreacted in the same manner as in Example 32

Sources & evidence

ORD record
ord-b0e239265db3485ea5e895fc55e42f4c
Source dataset
uspto-grants-1997_01
Patent number
US05591752

Reaction notes

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