HuagongsheHuagongshe Chemistry Print Report · For research reference only
(E)-3-[4-[5-methyl-2-(2-naphthyl)-4-oxazolylmethoxy]phenyl]-2-propen-1-ol → (E)-3-[4-[5-methyl-2-(2-naphthyl)-4-oxazolylmethoxy]phenyl]-2-propen-1-al
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | (E)-3-[4-[5-methyl-2-(2-naphthyl)-4-oxazolylmethoxy]phenyl]-2-propen-1-ol | HCID 23361385 | — |
| Catalyst | HCID 178418406 | HCID 178418406 | — |
| Product | (E)-3-[4-[5-methyl-2-(2-naphthyl)-4-oxazolylmethoxy]phenyl]-2-propen-1-al | HCID 23361378 | — |
Reaction Steps
According to the method described for Reference Example 34, (E)-3-[4-[5-methyl-2-(2-naphthyl)-4-oxazolylmethoxy]phenyl]-2-propen-1-ol was subjected to oxidation with activated manganese dioxide to give (E)-3-[4-[5-methyl-2-(2-naphthyl)-4-oxazolylmethoxy]phenyl]-2-propen-1-al. Recrystallization from chloroform-ether gave colorless prisms, m.p.179°-180° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05591862 |
| Source dataset | uspto-grants-1997_01 |
| ORD ID | ord-69e2e41e67f44dc285f3f6b5194965db |
| Source note | uspto-grants-1997_01 |