2-Amino-5-bromopyridine → HCID 54526953, compound

HRID 233719Notes

Reaction equation

HRID 233719 reaction equation
[C:1]([N:8]1C=CN=C1)([N:3]1[CH:7]=[CH:6][N:5]=[CH:4]1)=[S:2].[NH2:13][C:14]1[CH:19]=[CH:18][C:17]([Br:20])=[CH:16][N:15]=1>C(#N)C>[NH2:13][C:14]1[C:19]([NH:8][C:1]([N:3]2[CH:7]=[CH:6][N:5]=[CH:4]2)=[S:2])=[CH:18][C:17]([Br:20])=[CH:16][N:15]=1

Participants

4

Reactant 2

HCID 706222-Amino-5-bromopyridineHCID 802641,1'-Thiocarbonyldiimidazole

Product 1

HCID 54526953HCID 54526953, compound

Reagents, catalysts & solvents 1

HCID 6342AcetonitrileSolvent

Procedure

A solution of 1,1'-thiocarbonyldiimidazole (17.8 G, 0.1 m) and 2-amino-5-bromopyridine (17.3 g, 0.1 m) in acetonitrile (150 mL) was stirred at room temperature for 2 hours. To this suspension was added the material described below.

Workup

  1. additionTo this suspension was added the material

Sources & evidence

ORD record
ord-2e9e4bdf7eb74c24b0491f44b4327cc7
Source dataset
uspto-grants-1997_01
Patent number
US05593993

Reaction notes

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