Bromide ion → Spiro[2.5]octan-5-one

HRID 2339403Notes

Reaction equation

HRID 2339403 reaction equation
[Br-:11].[CH2:12]([CH3:13])[Mg+:14].[CH2:1]([O:2][C:4]1=[CH:5][C:6](=[O:10])[CH2:7][CH2:8][CH2:9]1)[CH3:3].[CH3:15][CH:16]([CH3:17])[O-:18].[CH3:20][CH:21]([CH3:22])[O-:23].[CH3:24][CH:25]([CH3:26])[O-:27].[CH3:28][CH:29]([CH3:30])[O-:31].[Ti+4:19]>>[C:4]12([CH2:5][C:6](=[O:10])[CH2:7][CH2:8][CH2:9]1)[CH2:12][CH2:13]2

Participants

6

Reactant 5

HCID 259Bromide ionHCID 792163-Ethoxycyclohex-2-ene-1-oneHCID 114942Titanium cation (4+)HCID 3260420Isopropanolate4×HCID 178461628HCID 178461628, compound

Product 1

HCID 12153480Spiro[2.5]octan-5-one

Sources & evidence

ORD record
ord-2b94b417d6ec47acba2b8a4a14ab754d
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (10/10)

Reaction notes

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