HuagongsheHuagongshe Chemistry Print Report · For research reference only
Benzoyl Peroxide → Diisobutylene Isopropenylphosphonic Acid
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Benzoyl Peroxide | HCID 7187 | — |
| Reactant | 2,4,4-Trimethyl-1-pentene | HCID 7868 | — |
| Reactant | Isopropenylphosphonic acid | HCID 557541 | — |
| Solvent | 1,2-Dimethoxyethane | HCID 8071 | — |
| Product | Diisobutylene Isopropenylphosphonic Acid | HCID 131719388 | — |
Reaction Steps
A high pressure autoclave was charged with 0.11 moles of isopropenylphosphonic acid and 0.132 moles of diisobutylene in ethylene glycol dimethyl ether. The components were reacted for 4 hours at 80° to 82° C. Benzoyl peroxide was used as the polymer initiator. 13C and 31P nuclear magnetic resonance spectra indicated approximately 10 to 30% incorporation of diisobutylene into the polymer reaction product.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05594084 |
| Source dataset | uspto-grants-1997_01 |
| ORD ID | ord-0a2930ecf82341d0b3c4f1d41f927732 |
| Source note | uspto-grants-1997_01 |