反应详情

温度

320 °C

Activated carbon (25 g, 1/8" (0.32 mm) diameter pellets) and deionized water (5 g) are loaded into a 1" (2.54 cm) OD×12" (30.5 cm) length Inconel™ 600 nickel alloy tube. The reactor temperature is raised to 320° C. and the reactor pressure adjusted to 230 psig (1690 kPa). (CF3)2CHCF2OCH3 (ether A, 9.2 g) and a solution of (CF3)2CHCO2H (2.0 g) in water (6 mL) are independently and continuously fed to the reactor over 3 hours. After the feed flow is stopped, the reactor is flushed with deionized water (10 g) . The reactor effluent is scrubbed to remove HF. The product includes both HFC-236fa and CF3CH=CF2 (HFC-1225zc).

1. customthe reactor is flushed with deionized water (10 g)
2. customto remove HF