Acetone → Ethyl 1-p-methylbenzyl-2-oxocyclopentane carboxylate

HRID 2344154Notes

Reaction equation

HRID 2344154 reaction equation
[C:12](=[O:13])([O-:14])[O-:15].[CH3:18][c:19]1[cH:20][cH:21][c:22]([CH2:23][Br:24])[cH:25][cH:26]1.[CH3:27][C:28](=[O:29])[CH3:30].[K+:16].[K+:17].[O:1]=[C:2]1[CH:3]([C:7](=[O:8])[O:9][CH2:10][CH3:11])[CH2:4][CH2:5][CH2:6]1>>[O:1]=[C:2]1[C:3]([C:7](=[O:8])[O:9][CH2:10][CH3:11])([CH2:23][c:22]2[cH:21][cH:20][c:19]([CH3:18])[cH:26][cH:25]2)[CH2:4][CH2:5][CH2:6]1

Participants

6

Reactant 5

HCID 180AcetoneHCID 813Potassium Cation2×HCID 7721p-Xylyl bromideHCID 19660Carbonate IonHCID 69136Ethyl 2-oxocyclopentanecarboxylate

Product 1

HCID 12163287Ethyl 1-p-methylbenzyl-2-oxocyclopentane carboxylate

Sources & evidence

ORD record
ord-3eedf540c16844b3859fc19092fca46c
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (10/10)

Reaction notes

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