Acetate → 1-(1H-inden-2-yl)-2,3-dimethylindole

HRID 2344964Notes

Reaction equation

HRID 2344964 reaction equation
[Br:26][C:27]1=[CH:31][c:30]2[c:29]([cH:35][cH:34][cH:33][cH:32]2)[CH2:28]1.[CH2:1]1[C:2]([n:10]2[cH:11][cH:12][cH:13][cH:14]2)=[CH:3][c:4]2[cH:5][cH:6][cH:7][cH:8][c:9]21.[CH3:15][c:16]1[nH:17][c:18]2[cH:19][cH:20][cH:21][cH:22][c:23]2[c:24]1[CH3:25].[CH3:53][O:54][CH2:55][CH2:56][O:57][CH3:58].[CH3:59][c:60]1[cH:61][cH:62][cH:63][cH:64][cH:65]1.[K+:41].[K+:42].[K+:43].[O-:45][C:46]([CH3:47])=[O:48].[O-:49][C:50]([CH3:51])=[O:52].[P:36]([O-:37])([O-:38])([O-:39])=[O:40].[Pd+2:44]>>[CH2:1]1[C:2]([n:17]2[c:16]([CH3:15])[c:24]([CH3:25])[c:23]3[c:18]2[cH:19][cH:20][cH:21][cH:22]3)=[CH:3][c:4]2[cH:5][cH:6][cH:7][cH:8][c:9]21

Participants

10

Reactant 9

HCID 175Acetate2×HCID 813Potassium Cation3×HCID 1061PhosphateHCID 1140TolueneHCID 70532,3-DimethylindoleHCID 80711,2-DimethoxyethaneHCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)HCID 5755861H-Indene, 2-bromo-HCID 180083501-(1H-inden-2-yl)-1H-pyrrole

Product 1

HCID 695021801-(1H-inden-2-yl)-2,3-dimethylindole

Sources & evidence

ORD record
ord-7b7798e70422445b8b83ee279e4afad8
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (10/10)

Reaction notes

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