HCID 22572976, compound → 4-tert-Butyl-5-thiocyanato-benzene-1,2-diamine

HRID 23487Notes

Reaction equation

HRID 23487 reaction equation
[C:1]([C:5]1[C:6]([S:15][C:16]#[N:17])=[CH:7][C:8]([N+:12]([O-])=O)=[C:9]([NH2:11])[CH:10]=1)([CH3:4])([CH3:3])[CH3:2].[H][H]>[Ni]>[C:1]([C:5]1[CH:10]=[C:9]([NH2:11])[C:8]([NH2:12])=[CH:7][C:6]=1[S:15][C:16]#[N:17])([CH3:4])([CH3:2])[CH3:3]

Participants

4

Reactant 2

HCID 22572976HCID 22572976, compoundHCID 178418361HCID 178418361, compound

Product 1

HCID 225729824-tert-Butyl-5-thiocyanato-benzene-1,2-diamine

Reagents, catalysts & solvents 1

HCID 935NickelCatalyst

Procedure

5-tert-Butyl-2-nitro-4-thiocyanato-phenylamine (prepared in Example QQ-2; 3 g, 12 mmol) was hydrogenated using Raney nickel (0.75 g) in the presence of hydrogen as described in General Method 3. MS(APCI): 222(M+H).

Sources & evidence

ORD record
ord-58c3a9b280e84bafba5460fc6f8032f7
Source dataset
uspto-grants-2005_02
Patent number
US06852711B2

Reaction notes

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