Methanethiol → HCID 19705090, compound

HRID 234966Notes

Reaction equation

HRID 234966 reaction equation
[NH2:1][C:2]1[N:7]=[C:6]([NH2:8])[C:5]([C:9]2[CH:14]=[C:13]([N+]([O-])=O)[CH:12]=[CH:11][C:10]=2[Cl:18])=[C:4]([CH3:19])[N:3]=1.N([O-])=O.[Na+].[CH3:24][SH:25]>[Cu]>[NH2:1][C:2]1[N:7]=[C:6]([NH2:8])[C:5]([C:9]2[CH:14]=[C:13]([S:25][CH3:24])[CH:12]=[CH:11][C:10]=2[Cl:18])=[C:4]([CH3:19])[N:3]=1

Participants

5

Reactant 3

HCID 878MethanethiolHCID 19705068HCID 19705068, compoundHCID 23668193Sodium Nitrite

Product 1

HCID 19705090HCID 19705090, compound

Reagents, catalysts & solvents 1

HCID 23978CopperCatalyst

Procedure

This compound was prepared in a similar manner to the compound of Example 54 by reaction of the diazonium salt with methanethiol in the presence of copper powder, mp. 194°-198° C.

Sources & evidence

ORD record
ord-176861d7c34d4c4b87a4c06ef8d69aaa
Source dataset
uspto-grants-1997_01
Patent number
US05597827

Reaction notes

Loading…