HCID 54236511, compound → HCID 54462733, compound

HRID 234987Notes

Reaction equation

HRID 234987 reaction equation
[C:1]([C:3]1[CH:8]=[CH:7][C:6]([C:9]2[CH:14]=[CH:13][C:12]([O:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][C:21]([O:23][CH3:24])=[O:22])=[C:11]([N+:25]([O-])=O)[CH:10]=2)=[CH:5][CH:4]=1)#[N:2].[H][H]>CO.[Pd]>[NH2:25][C:11]1[CH:10]=[C:9]([C:6]2[CH:5]=[CH:4][C:3]([C:1]#[N:2])=[CH:8][CH:7]=2)[CH:14]=[CH:13][C:12]=1[O:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][C:21]([O:23][CH3:24])=[O:22]

Participants

5

Reactant 2

HCID 54236511HCID 54236511, compoundHCID 178418361HCID 178418361, compound

Product 1

HCID 54462733HCID 54462733, compound

Reagents, catalysts & solvents 2

HCID 23938PalladiumCatalystHCID 887MethanolSolvent

Procedure

Prepared from 4-cyano-4'-(5-methoxycarbonyl-pentyloxy)-3'-nitro-biphenyl by hydrogenating with hydrogen under 5 bars of pressure in methanol in the presence of 10% palladium/charcoal at ambient temperature.

Sources & evidence

ORD record
ord-ef9d8d5275b64755ac599226a478948d
Source dataset
uspto-grants-1997_01
Patent number
US05597825

Reaction notes

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