Sodium Hydroxide → HCID 53737769, compound

HRID 2351183Notes

Reaction equation

HRID 2351183 reaction equation
[CH3:1][O:2][N:3]=[C:4]([C:9]1[CH:14]=[CH:13][CH:12]=[C:11]([O:15][CH3:16])[CH:10]=1)[C:5]([O:7]C)=[O:6].[OH-].[Na+]>>[CH3:1][O:2][N:3]=[C:4]([C:9]1[CH:14]=[CH:13][CH:12]=[C:11]([O:15][CH3:16])[CH:10]=1)[C:5]([OH:7])=[O:6]

Participants

3

Reactant 2

HCID 14798Sodium HydroxideHCID 53780059HCID 53780059, compound

Product 1

HCID 53737769HCID 53737769, compoundYield 86.7%

Procedure

Methyl 2-methoxyimino-2-(3-methoxyphenyl)acetate (anti isomer) (1.6 g.) and a 2N aqueous solution of sodium hydroxide (4 ml.) were treated according to a similar manner to that of Preparation 5-3)(c) to give colorless prisms of 2-methoxyimino-2-(3-methoxyphenyl)acetic acid (anti isomer) (1.3 g.), mp 97° to 98° C.

Workup

  1. customof Preparation 5-3)(c)

Sources & evidence

ORD record
ord-30c8cbf81daa4a3ea6b9357b21971900
Source dataset
uspto-grants-1989_10
Patent number
US04871860

Reaction notes

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