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HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
HRID 2351265Erstellt: 25. Oktober 2026

Rhodium → Rhodium Tribenzylphosphine

https://huagongshe.com/reaction/2351265

Reaktionsgleichung

Beteiligte Stoffe

RolleNameHCIDEinwaage
EduktRhodiumHCID 23948—
EduktPhosphine, tris(phenylmethyl)-HCID 82101—
LösungsmittelTexanolHCID 6490—
ProduktRhodium TribenzylphosphineHCID 86743422—

Reaktionsbedingungen

Temperatur125 °C

Reaktionsschritte

A catalyst charge comprised of 31.25 mg of rhodium (as rhodium 2-ethylhexanoate) and varying amounts of tribenzylphosphine (as noted in Table 3) dissolved in 0.2 liter of Texanol® solvent was charged to the reactor system described above. The reactor was maintained at 125° C. and operated continuously for seven hours. The reaction was conducted according to the general procedure set forth above. Operating parameters and reaction results are set forth in Table 3.

Herkunft & Nachweise

DOI10.6084/m9.figshare.5104873.v1
PatentnummerUS04873213
Quelldatensatzuspto-grants-1989_10
ORD IDord-10c543711fbd4d2286fad605ff01ec96
Quellennotizuspto-grants-1989_10