HuagongsheHuagongshe Chemistry Print Report · For research reference only
L-Glutamic acid dibenzyl ester tosylate → 3-(2,3-dimethoxy-5-methylbenzoquinon-6-yl)-propionyl-L-glutamic acid
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | L-Glutamic acid dibenzyl ester tosylate | HCID 13233366 | — |
| Reactant | p-Nitropenyl 3-(2,3-dimethoxy-5-methyl-1,4-benzoquinon-6-yl)propionate | HCID 14180316 | — |
| Product | 3-(2,3-dimethoxy-5-methylbenzoquinon-6-yl)-propionyl-L-glutamic acid | HCID 13518506 | 25.6% |
Reaction Steps
Using p-nitrophenyl 3-(2,3-dimethoxy-5-methyl-1,4-benzoquinon-6-yl)propionate (187 mg, 0.5 mmol) and dibenzyl L-glutamate p-toluenesulfonate (250 mg, 0.5 mmol) and following the procedure of Example 4, there was obtained 3-(2,3-dimethoxy-5-methylbenzoquinon-6-yl)propionyl-L-glutamic acid (49 mg).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04874752 |
| Source dataset | uspto-grants-1989_10 |
| ORD ID | ord-b04fad3814594be390043ba45347f86b |
| Source note | uspto-grants-1989_10 |