Diethyl Ether → HCID 86743455, compound

HRID 2352058Notes

Reaction equation

HRID 2352058 reaction equation
[F:1][C:2]([F:8])([F:7])[S:3]([O-:6])(=[O:5])=[O:4].[CH3:9][C:10]1[Te:11][C:12]2[CH:19]=[CH:18][C:17]([CH3:20])=[CH:16][C:13]=2[N+:14]=1[CH3:15].[CH2:21]([O:23][CH:24](OCC)OCC)[CH3:22].C(OCC)C>C1C(O)=CC=CC=1C>[F:1][C:2]([F:8])([F:7])[S:3]([O-:6])(=[O:5])=[O:4].[CH2:21]([O:23][CH:24]=[CH:9][C:10]1[Te:11][C:12]2[CH:19]=[CH:18][C:17]([CH3:20])=[CH:16][C:13]=2[N+:14]=1[CH3:15])[CH3:22]

Participants

5

Reactant 3

HCID 3283Diethyl EtherHCID 31214Ethyl orthoformateHCID 14324127HCID 14324127, compound

Product 1

HCID 86743455HCID 86743455, compound

Reagents, catalysts & solvents 1

HCID 342M-CresolSolvent

Conditions

Temperature
140 °C

Procedure

2,3,5-Trimethylbenzotellurazolium trifluoromethanesulfonate (Example 33) (0.84 g, 0.002 mole) was dissolved in m-cresol (1 ml). Triethoxymethane (0.89 g, 0.006 mole) was added, and the reaction mixture was heated in a 140° C. oil bath for five minutes. After cooling, diethyl ether (25 ml) was added with stirring. The solid was isolated by filtration, washed with diethyl ether, and dried at 40° C. under vacuum. Yield 0.85 g (89% of theory). The nuclear magnetic resonance spectra of the sample were in agreement with that expected for the structural formula.

Workup

  1. temperatureAfter cooling
  2. customThe solid was isolated by filtration
  3. washwashed with diethyl ether
  4. customdried at 40° C. under vacuum

Sources & evidence

ORD record
ord-f6fc9b6d14f4403cb886842cf7eae90d
Source dataset
uspto-grants-1989_10
Patent number
US04874866

Reaction notes

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