HuagongsheHuagongshe Chemistry Print Report · For research reference only
Hexamethylenetetramine → HCID 14250980, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Hexamethylenetetramine | HCID 4101 | — |
| Reactant | Permanganate | HCID 24401 | — |
| Reactant | 5-(Aminomethyl)naphthalene-2-sulfonic acid | HCID 14250978 | — |
| Reactant | 5-Formyl-2-naphthalenesulfonic acid | HCID 15253783 | — |
| Product | HCID 14250980 | HCID 14250980 | — |
Reaction Steps
The 1-aminomethylnaphthalene-6-sulphonic acid can be converted into 1-formylnaphthalene-6-sulphonic acid in a manner which is known per se by a Sommelet reaction (see, for example, Houben Weyl, Methoden der Organischen Chemie (Methods of Organic Chemistry), 4th edition, volume 7/1 page 198 or Organic Reactions 8, 197 (1954)), that is to say by reaction with hexamethylenetetramine. The 1-formylnaphthalene-6-sulphonic acid is in turn oxidized by processes known for the oxidation of aldehydes to carboxylic acids (see, for example, Houben Weyl loc. cit. volume 8, pages 407-413), for example by oxidation with permanganate (see, for example, Houben Weyl, volume 4 I/b, pages 615-621), to give 1-carboxynaphthalene-6-sulphonic acid.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04874892 |
| Source dataset | uspto-grants-1989_10 |
| ORD ID | ord-fb845736c3584a16a7b8b0af09f0e68d |
| Source note | uspto-grants-1989_10 |