m-Chloroperbenzoic acid → HCID 14821696, compound

Participants

Reaction Steps

To the above carbamate is added a solution of m-chloroperbenzoic acid (431 mg, 2.5 mmol) in 10 ml of methylene chloride. After 15 min, the reaction mixture is extracted with KHCO3 and Na2SO3 and stripped. The product is purified by prep. TLC eluting with ethyl acetate (neat). The upper band is collected to give (E)-3-fluoro-3-hexylsulfinyl-2-propenyl dimethylcarbamate (cpd. 28, Table A).

Provenance & Evidence