Sodium Hydroxide → HCID 53737769, compound

HRID 2352710Notes

Reaction equation

[CH3:1][O:2][N:3]=[C:4]([C:9]1[CH:14]=[CH:13][CH:12]=[C:11]([O:15][CH3:16])[CH:10]=1)[C:5]([O:7]C)=[O:6].[OH-].[Na+]>>[CH3:1][O:2][N:3]=[C:4]([C:9]1[CH:14]=[CH:13][CH:12]=[C:11]([O:15][CH3:16])[CH:10]=1)[C:5]([OH:7])=[O:6]

Participants

Reactant 2

HCID 14798Sodium Hydroxide

HCID 53780059HCID 53780059, compound

Product 1

HCID 53737769HCID 53737769, compoundYield 86.7%

Procedure

Methyl 2-methoxyimino-2-(3-methoxyphenyl)acetate (anti isomer) (1.6 g.) and a 2N aqueous solution of sodium hydroxide (4 ml.) were treated according to a similar manner to that of Preparation 5-3) (c) to give colorless prisms of 2-methoxyimino-2-(3-methoxyphenyl)acetic acid (anti isomer) (1.3 g.), mp 97° to 98° C.

Sources & evidence

ORD record: ord-ff5ce4d1389f4b87acf28974554b2f69
Source dataset: uspto-grants-1989_10
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04877873

Reaction notes

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