HCID 86602372, compound → HCID 86602371, compound

HRID 2354274Notes

Reaction equation

HRID 2354274 reaction equation
[CH3:1][O:2][C:3]1[CH:4]=[C:5](/[CH:15]=[CH:16]/[C:17]([O:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][O:28][C:29](=[O:81])[C:30]([CH:71]([N+:78]([O-])=O)[C:72]2[CH:77]=[CH:76][CH:75]=[CH:74][CH:73]=2)([CH:61]([N+:68]([O-])=O)[C:62]2[CH:67]=[CH:66][CH:65]=[CH:64][CH:63]=2)[C:31]([O:33][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][CH2:40][CH2:41][O:42][C:43](=[O:60])/[CH:44]=[CH:45]/[C:46]2[CH:51]=[CH:50][C:49]([O:52][CH2:53][CH2:54][CH2:55][CH2:56][CH3:57])=[C:48]([O:58][CH3:59])[CH:47]=2)=[O:32])=[O:18])[CH:6]=[CH:7][C:8]=1[O:9][CH2:10][CH2:11][CH2:12][CH2:13][CH3:14]>[Zn]>[CH3:59][O:58][C:48]1[CH:47]=[C:46](/[CH:45]=[CH:44]/[C:43]([O:42][CH2:41][CH2:40][CH2:39][CH2:38][CH2:37][CH2:36][CH2:35][CH2:34][O:33][C:31](=[O:32])[C:30]([CH:61]([NH2:68])[C:62]2[CH:67]=[CH:66][CH:65]=[CH:64][CH:63]=2)([CH:71]([NH2:78])[C:72]2[CH:73]=[CH:74][CH:75]=[CH:76][CH:77]=2)[C:29]([O:28][CH2:27][CH2:26][CH2:25][CH2:24][CH2:23][CH2:22][CH2:21][CH2:20][O:19][C:17](=[O:18])/[CH:16]=[CH:15]/[C:5]2[CH:6]=[CH:7][C:8]([O:9][CH2:10][CH2:11][CH2:12][CH2:13][CH3:14])=[C:3]([O:2][CH3:1])[CH:4]=2)=[O:81])=[O:60])[CH:51]=[CH:50][C:49]=1[O:52][CH2:53][CH2:54][CH2:55][CH2:56][CH3:57]

Participants

3

Reactant 1

HCID 86602372HCID 86602372, compound

Product 1

HCID 86602371HCID 86602371, compound

Reagents, catalysts & solvents 1

HCID 23994ZincCatalyst

Procedure

Preparation can be carried out analogously to Synthetic Example 1 using 1.07 g (1.00 mmol) of bis [8-({(2E)-3-[3-methoxy-4-(pentyloxy)phenyl)prop-2-enoyl}oxy)octyl]2,2-bis(nitrobenzyl)malonate, 1.62 g (6.00 mmol) Ferric chloride hexahydrate and 0.65 g (10.00 mmol) Zinc powder yield bis [8-({(2E)-3-[3-methoxy-4-(pentyloxy)phenyl)prop-2-enoyl}oxy)octyl]2,2-bis(aminobenzyl)malonate.

Workup

  1. customPreparation

Sources & evidence

ORD record
ord-fdd96508eaa246eb9761ccf4c75a1e82
Source dataset
uspto-grants-2010_07
Patent number
US07750185B2

Reaction notes

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