Toluene → HCID 66990270, compound

Participants

Reaction Conditions

Reaction Steps

To a solution of 17 (0.18 g, 0.65 mmol) in 25 mL dry CH2Cl2 at 25° C. under inert atmosphere was added H2PtCl6.xH2O (0.001 g), followed by trichlorosilane (0.88 g, 6.5 mmol). The reaction solution was warmed to 30° C. and monitored by NMR until the completion of reaction after 4 h. Removal of the solvent in vacuum yielded a oil. 20 mL dry toluene was added to the residue and filtered into a Schlenk flask by cannula. The filtrate was concentrated under vacuum to give 18 as a oil. Yield, 98%. 1H NMR (benzene): δ0.90 (t, J=8 Hz, 2H), 1.55 (m, 2H), 2.20 (t, J=8 Hz, 2H), 6.75-6.83 (m, 4H), 6.98-7.14 (m, 10H).

Provenance & Evidence