2,5-Dibromopyridine → HCID 12269210, compound

HRID 2355003Notes

Reaction equation

HRID 2355003 reaction equation
[CH3:1][S:2]([C:5]1[CH:10]=[CH:9][C:8]([S:11]([CH3:14])(=O)=O)=[CH:7][N:6]=1)(=O)=O.BrC1C=CC(Br)=CN=1.C[S-].[Na+]>>[CH3:1][S:2][C:5]1[CH:10]=[CH:9][C:8]([S:11][CH3:14])=[CH:7][N:6]=1

Participants

4

Reactant 3

HCID 693532,5-DibromopyridineHCID 4378561Sodium methanethiolateHCID 131026752,5-Bis(methylsulfonyl)pyridine

Product 1

HCID 12269210HCID 12269210, compound

Procedure

The 2,5-bismethanesulfonylpyridine was obtained by reacting 2,5-dibromopyridine with sodium thiomethoxide to obtain 2,5-bis-methylthiopyridine, and then oxidizing it with metachloroperbenzoic acid. The reaction between 2,5-dibromopyridine and sodium methoxide and the oxidation of 2,5-bis-methylthiopyridine with metachloroperbenzoic acid may be carried out according to ordinary methods.

Sources & evidence

ORD record
ord-caca9ba1fd6f43fd8ac1a87eefb2b0c5
Source dataset
uspto-grants-2010_07
Patent number
US07754743B2

Reaction notes

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