Stannous Chloride → 5-Methyl-2-p-tolylsulfanyl-phenylamine

HRID 2358597Notes

Reaction equation

[CH3:1][C:2]1[CH:7]=[CH:6][C:5]([S:8][C:9]2[CH:14]=[CH:13][C:12]([CH3:15])=[CH:11][CH:10]=2)=[C:4]([N+:16]([O-])=O)[CH:3]=1.Cl[Sn]Cl>>[CH3:1][C:2]1[CH:7]=[CH:6][C:5]([S:8][C:9]2[CH:14]=[CH:13][C:12]([CH3:15])=[CH:11][CH:10]=2)=[C:4]([NH2:16])[CH:3]=1

Participants

Reactant 2

HCID 24479Stannous Chloride

HCID 684576704-Methyl-2-nitro-1-p-tolylsulfanyl-benzene

Product 1

HCID 431689305-Methyl-2-p-tolylsulfanyl-phenylamine

Procedure

The product from Example 47a was reduced with SnCl2 following the procedure from Example 1f giving the title compound.

Sources & evidence

ORD record: ord-300468a6a43c4ebd9eee5b12bd2fce4d
Source dataset: uspto-grants-2010_07
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US07763731B2

Reaction notes

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