Stannous Chloride → HCID 68459467, compound

HRID 2358756Notes

Reaction equation

HRID 2358756 reaction equation
[Cl:1][C:2]1[CH:20]=[CH:19][C:5]([O:6][C:7]2[CH:8]=[C:9]([CH:16]=[CH:17][CH:18]=2)[C:10]([NH:12][CH2:13][CH2:14][CH3:15])=[O:11])=[C:4]([N+:21]([O-])=O)[CH:3]=1.Cl[Sn]Cl>>[NH2:21][C:4]1[CH:3]=[C:2]([Cl:1])[CH:20]=[CH:19][C:5]=1[O:6][C:7]1[CH:8]=[C:9]([CH:16]=[CH:17][CH:18]=1)[C:10]([NH:12][CH2:13][CH2:14][CH3:15])=[O:11]

Participants

3

Reactant 2

HCID 24479Stannous ChlorideHCID 68456871HCID 68456871, compound

Product 1

HCID 68459467HCID 68459467, compoundYield 77%

Procedure

The product from Example 175a (0.88 g, 2.6 mmol) was reacted with SnCl2 as described in Example 1f to give the title compound (0.61 g, 76%).

Sources & evidence

ORD record
ord-e63d4efc572e46318df006eb9d3bdd96
Source dataset
uspto-grants-2010_07
Patent number
US07763731B2

Reaction notes

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