Stannous Chloride → HCID 68455863, compound

HRID 2358769Notes

Reaction equation

[CH2:1]([O:8][C:9](=[O:30])[NH:10][CH:11]([C:13]1[CH:18]=[CH:17][C:16]([O:19][C:20]2[CH:25]=[CH:24][C:23]([Cl:26])=[CH:22][C:21]=2[N+:27]([O-])=O)=[CH:15][CH:14]=1)[CH3:12])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.Cl[Sn]Cl>>[CH2:1]([O:8][C:9](=[O:30])[NH:10][CH:11]([C:13]1[CH:18]=[CH:17][C:16]([O:19][C:20]2[CH:25]=[CH:24][C:23]([Cl:26])=[CH:22][C:21]=2[NH2:27])=[CH:15][CH:14]=1)[CH3:12])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

Participants

Reactant 2

HCID 24479Stannous Chloride

HCID 68460732HCID 68460732, compound

Product 1

HCID 68455863HCID 68455863, compoundYield 80.8%

Procedure

The product from Example 182b (1.0 g, 2.34 mmol) was reacted with SnCl2 as described in Example 237E to give the title compound (0.75 g, 80%).

Sources & evidence

ORD record: ord-e5723c33607e4dd695e75f5ae1717751
Source dataset: uspto-grants-2010_07
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US07763731B2

Reaction notes

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