2-Hydroxyethyl acrylate → Demannose

HRID 2361539Notes

Reaction equation

HRID 2361539 reaction equation
C=CC[O:4][C@H:5]1[O:10][C@H:9]([CH2:11][OH:12])[C@@H:8]([OH:13])[C@H:7]([OH:14])[C@@H:6]1[OH:15].OCCOC(=O)C=C>>[O:4]=[CH:5][C@H:6]([C@H:7]([C@@H:8]([C@@H:9]([CH2:11][OH:12])[OH:10])[OH:13])[OH:14])[OH:15]

Participants

3

Reactant 2

HCID 131652-Hydroxyethyl acrylateHCID 11183597Allyl alpha-D-mannopyranoside

Product 1

HCID 161658Demannose

Procedure

An 80 mol % mannose polymer was prepared as in Example A4, except that the amount of allyl-α-D-mannopyranoside was 3.54 g (16 mmol) and the amount of 2-hydroxyethylacrylate was 0.68 g (5.85 mmol).

Sources & evidence

ORD record
ord-b5eefd5e81af4356bddaf0f1edef4d89
Source dataset
uspto-grants-2014_04
Patent number
US08691517B2

Reaction notes

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