HCID 12926534, compound → HCID 131715057, compound

HRID 236267Notes

Reaction equation

HRID 236267 reaction equation
[C:1]([C:5]([O:22][SiH:23]([CH3:25])[CH3:24])([C:15]1[CH:20]=[CH:19][CH:18]=[C:17]([CH3:21])[CH:16]=1)[CH2:6][NH:7][C:8](SC)=[CH:9][N+:10]([O-:12])=[O:11])([CH3:4])([CH3:3])[CH3:2].[CH3:26][N:27]([CH2:29][C:30]1[S:34][C:33]([CH2:35][S:36][CH2:37][CH2:38][NH2:39])=[CH:32][C:31]=1[CH3:40])[CH3:28]>>[C:1]([C:5]([O:22][SiH:23]([CH3:25])[CH3:24])([C:15]1[CH:20]=[CH:19][CH:18]=[C:17]([CH3:21])[CH:16]=1)[CH2:6][NH:7][C:8]([NH:39][CH2:38][CH2:37][S:36][CH2:35][C:33]1[S:34][C:30]([CH2:29][N:27]([CH3:26])[CH3:28])=[C:31]([CH3:40])[CH:32]=1)=[CH:9][N+:10]([O-:12])=[O:11])([CH3:3])([CH3:4])[CH3:2]

Participants

3

Reactant 2

HCID 12926534HCID 12926534, compoundHCID 131715058HCID 131715058, compound

Product 1

HCID 131715057HCID 131715057, compoundYield 87%

Procedure

In the same manner as in Example 6-(2), 3.8 g of 1-{[2-(tert.-butyl)dimethylsilyloxy-2-(3-methylphenyl)ethyl]amino}-1-methylthio-2-nitroethene and 2.6 g of 2-{[5-(dimethylamino)methyl-4-methyl-2-thienyl]methylthio}ethylamine were reacted and treated to obtain 4.6 g (yield 87%) of oily N-[2-(tert.-butyl)dimethylsilyloxy-2-(3-methylphenyl)ethyl]-N'-{2-[[5-(dimethylamino)methyl-4-methyl-2-thienyl]methylthio]ethyl}-2-nitro-1,1-ethenediamine.

Workup

  1. additiontreated

Sources & evidence

ORD record
ord-d7bbea41c878489a8611cc32862a41aa
Source dataset
uspto-grants-1987_02
Patent number
US04643849

Reaction notes

Loading…