HRID236418

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：CC(=O)Nc1cc2c(cc1[N+](=O)[O-])[C@@H](N1CCCC1=O)[C@H](O)C(C)(C)O2

HCID13704347

未命名化合物

PRODUCTS

生成物

结构：CC(=O)Nc1cc2c(cc1[N+](=O)[O-])OC(C)(C)[C@@H](O)[C@@H]2N1CCCC1=O

HCID13704345

未命名化合物

PROCEDURE

实验过程

6-amino-7-nitro-3,4-dihydro-trans-4-(2-ketopyrrolidinyl)2,2-dimethyl-2H-benzo[b]pyran-3-ol or a pharmaceutically acceptable salt thereof; 6-nitro-7-acetamido-3,4-dihydro-trans-4-(2-ketopyrrolidinyl)-2,2-dimethyl-2H-benzo[b]pyran-3-ol; 6-nitro-7-amino-3,4-dihydro-trans-4-(2-ketopyrrolidinyl)-2,2-dimethyl-2H-benzo[b]pyran-3-ol or a pharmaceutically salt thereof; or 6-cyano-7-amino-3,4-dihydro-trans-4-(2-ketopyrrolidinyl)-2,2-dimethyl-2H-benzo[b]pyran-3-ol or a pharmaceutically acceptable salt thereof.

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-e9306b49a37147e7a673a19defdea576
来源数据集: uspto-grants-1987_02
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04644070
来源说明: uspto-grants-1987_02

反应 SMILES

[NH2:1][C:2]1[C:20]([N+:21]([O-:23])=[O:22])=[CH:19][C:5]2[O:6][C:7]([CH3:18])([CH3:17])[C@@H:8]([OH:16])[C@H:9]([N:10]3[CH2:14][CH2:13][CH2:12][C:11]3=[O:15])[C:4]=2[CH:3]=1.[N+](C1C(NC(=O)C)=C[C:30]2[O:31]C(C)(C)[C@@H](O)[C@H](N3CCCC3=O)[C:29]=2C=1)([O-])=O.[N+](C1C(N)=CC2OC(C)(C)[C@@H](O)[C@H](N3CCCC3=O)C=2C=1)([O-])=O.C(C1C(N)=CC2OC(C)(C)[C@@H](O)[C@H](N3CCCC3=O)C=2C=1)#N>>[C:30]([NH:1][C:2]1[C:20]([N+:21]([O-:23])=[O:22])=[CH:19][C:5]2[O:6][C:7]([CH3:17])([CH3:18])[C@@H:8]([OH:16])[C@H:9]([N:10]3[CH2:14][CH2:13][CH2:12][C:11]3=[O:15])[C:4]=2[CH:3]=1)(=[O:31])[CH3:29]