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HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 236673Generated: October 26, 2026

1,3-Butadiene → 3-Buten-2-ol

https://huagongshe.com/reaction/236673

Reaction equation

Participants

RoleNameHCIDCharge
Reactant1,3-ButadieneHCID 7845—
ReactantSulfolaneHCID 31347—
Product3-Buten-2-olHCID 1171660%
Product2-Buten-1-olHCID 2002426%

Reaction Conditions

Temperature100 °C

Reaction Steps

In accordance with Example 1, a homogeneous solution of 6.2 grams (0.11 moles) of butadiene and 100 milliliters of a 65 volume percent aqueous sulfolane solution were reacted in the presence of a cation exchanger sold under the trademark Lewatit SPC 118 at a temperature of 100° C. After agitating at 100° C. for 6 hours, 76 percent of the mixture had reacted. A yield of 60 percent 1-butene-3-ol and a yield of 26 percent 2-butene-1-ol (crotylalcohol) was obtained.

Provenance & Evidence

DOI10.6084/m9.figshare.5104873.v1
Patent numberUS04645863
Source datasetuspto-grants-1987_02
ORD IDord-aa74cbbdce7045b8b53dc7029ba5d8d2
Source noteuspto-grants-1987_02