Dimethyl N-cyanodithioiminocarbonate → HCID 178449194, compound

HRID 236710Notes

Reaction equation

HRID 236710 reaction equation
[C:1]([N:3]=[C:4](SC)[S:5][CH3:6])#[N:2].[CH2:9]([NH2:13])[C:10]#[C:11][CH3:12]>C(#N)C>[CH2:9]([NH:13][C:4](=[N:3][C:1]#[N:2])[S:5][CH3:6])[C:10]#[C:11][CH3:12]

Participants

4

Reactant 2

HCID 66289Dimethyl N-cyanodithioiminocarbonateHCID 12599998But-2-yn-1-amine

Product 1

HCID 178449194HCID 178449194, compound

Reagents, catalysts & solvents 1

HCID 6342AcetonitrileSolvent

Procedure

A solution of dimethyl cyanodithioimidocarbonate (10.00 g, 0.0684 mole) and 2-butyn-1-amine (4.73 g, 0.0684 mole) in acetonitrile (200 ml) was stirred at 25° for 0.5 hour, and then at reflux for 2.5 hours. The mixture was cooled, then filtered to yield the title compound B, mp 180°-183°.

Workup

  1. temperatureat reflux for 2.5 hours
  2. temperatureThe mixture was cooled
  3. filtrationfiltered

Sources & evidence

ORD record
ord-65bb8c2aaf864b26b26af07b9d621519
Source dataset
uspto-grants-1979_06
Patent number
US04157347

Reaction notes

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