HuagongsheHuagongshe Chemistry Print Report · For research reference only
p-Toluenesulfonic acid → Ethyl 4-[(2,6-dichlorophenyl)imino]-1-piperidinecarboxylate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | p-Toluenesulfonic acid | HCID 6101 | — |
| Reactant | O-Xylene | HCID 7237 | — |
| Reactant | 2,6-Dichloroaniline | HCID 11846 | — |
| Reactant | Ethyl 4-oxo-1-piperidinecarboxylate | HCID 34767 | — |
| Solvent | Water | HCID 962 | — |
| Product | Ethyl 4-[(2,6-dichlorophenyl)imino]-1-piperidinecarboxylate | HCID 23339072 | — |
Reaction Steps
A mixture of 171 parts of ethyl 4-oxo-1-piperidinecarboxylate, 162 parts of 2,6-dichlorobenzenamine, 800 parts of dimethylbenzene and 1 part of 4-methylbenzenesulfonic acid is stirred and refluxed with water-separator. The reaction mixture is evaporated, yielding 250 parts of ethyl 4-[(2,6-dichlorophenyl)imino]-1-piperidinecarboxylate as a residue.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04157393 |
| Source dataset | uspto-grants-1979_06 |
| ORD ID | ord-1d136abfa5994e3192fc77a159b4fa5d |
| Source note | uspto-grants-1979_06 |