Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Methacrylic Acid | HCID 4093 | — |
| Reactant | Iron | HCID 23925 | — |
| Reactant | Ferrous nitrate | HCID 9815404 | — |
| Solvent | Water | HCID 962 | — |
| Product | Iron(2+) methacrylate | HCID 57356750 | 90% |
Reaction Steps
For example, a method has been proposed, in which methacrylic acid, an alkaline metal and an iron salt such as iron nitrate are mixed in a solvent such as water, and iron methacrylate is produced by salt exchange (Patent Literature 1). Since this method has a difficulty in securely completing salt exchange, iron methacrylate is difficult to obtain in a high yield of 90% or higher. The method has further problems such as a reduction in purity due to contamination of iron methacrylate with impurities derived from nitric acid, and a rise in the cost because of necessity of filtration and drying processes. In the case where a hydroxyalkyl methacrylate is produced by using the prepared iron methacrylate as a catalyst, there are concern about problems, such as by-production of impurities, coloration and the like derived from nitric acid contained in the catalyst raw material.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US08697899B2 |
|---|
| Source dataset | uspto-grants-2014_04 |
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| ORD ID | ord-faa126c2e6514023991d1dce018ad3e9 |
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| Source note | uspto-grants-2014_04 |
|---|