Acetic Acid → HCID 86660597, compound

Participants

Reaction Steps

1-allyl-2,3-dibenzoyl-4-azido-4-deoxy-L-xylose 35 (12.0 g, 28.3 mmol) was dissolved in 5:1 methanol:THF (70 mL); to this solution was added sodium methoxide (650 μL of 25% solution, 2.83 mmol). The solution was stirred for 5 h, then to it was added acetic acid (175 μL, 3.11 mmol) and the reaction stirred for 1 min. The solvent was removed in vacuo to give 36 as a thick oil. The material was used without further purification.

Provenance & Evidence