Sodium Iodide → HCID 21313737, compound

Participants

Reaction Steps

A solution of 153 g of (25C) and 500 g of sodium iodide in 700 ml of dry acetone (distilled from anhydrous potassium carbonate) was refluxed under argon for 18 hours. The solvent was then removed by evaporation in vacuo. The residue was mixed with water and extracted three times with ether. The combined extract was dried over anhydrous magnesium sulfate and then evaporated in vacuo to yield 238 g of the desired product which had the following spectral properties: nmr (CDCl3) δ 0.9-2.8 (11H, m), 7.30 (1H, d, J=15 Hz) and 7.92 ppm (1H, d, J=15 Hz).

Provenance & Evidence