HCID 86736416, compound → HCID 21315520, compound

HRID 236872Notes

Reaction equation

HRID 236872 reaction equation
C(O)(=O)/C=C\C(O)=O.CN1CC[C@@H]2C3C=CC=CC=3OC3C=CC=CC=3[C@@H]2C1.C(O)(=O)/C=C\C(O)=O.[CH3:37][N:38]1[CH2:43]C[C@@H:41]2[C:44]3[CH:56]=[CH:55][CH:54]=[CH:53][C:45]=3[CH2:46][C:47]3[CH:52]=[CH:51][CH:50]=[CH:49][C:48]=3[C@@H:40]2[CH2:39]1>>[CH3:43][N:38]1[CH2:39][CH:40]2[C:48]3[CH:49]=[CH:50][CH:51]=[CH:52][C:47]=3[CH2:46][C:45]3[CH:53]=[CH:54][CH:55]=[CH:56][C:44]=3[CH:41]2[CH2:37]1

Participants

3

Reactant 2

HCID 86736416HCID 86736416, compoundHCID 86736418HCID 86736418, compound

Product 1

HCID 21315520HCID 21315520, compound

Procedure

cis-2-methyl-1,2,3,4,4a,13b-hexahydro-dibenz[2,3;6,7] oxepino[4,5-c]pyridine maleate, m.p. 174°-175° C.; cis-2-methyl-2,3,4,4a,9,13b-hexahydro-1H-dibenzo[1,2;5,6] cyclohepta[3,4-c]pyridine maleate, m.p. 207°-209° C. and the corresponding trans isomer (maleate salt), m.p. 175°-176° C.

Sources & evidence

ORD record
ord-167cfe38910d499aab4ad3bf3431d0ca
Source dataset
uspto-grants-1979_06
Patent number
US04158058

Reaction notes

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