HuagongsheHuagongshe Chemistry Print Report · For research reference only
Acrolein → 3-Oxa-tricyclo[6.2.1.02,7]undec-4-ene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Acrolein | HCID 7847 | — |
| Reactant | 2-Norbornene | HCID 10352 | — |
| Catalyst | Hydroquinone | HCID 785 | — |
| Product | 3-Oxa-tricyclo[6.2.1.02,7]undec-4-ene | HCID 13539909 | 50% |
Reaction Steps
56.4 g of norbornene, 16.8 g of acrolein and 0.5 g of hydroquinone were heated 15 hours at 190° in a stainless steel autoclave (pressure about 15 atm.). After evaporation a fractional distillation of the residue gave 22.5 g (yield 49%) of 3-oxa-tricyclo[6.2.1.02,7 ]undec-4-ene; b.p. 35°-7°/0.5 Torr.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04159258 |
| Source dataset | uspto-grants-1979_06 |
| ORD ID | ord-efa0042304f54649aed1f9382912908e |
| Source note | uspto-grants-1979_06 |