HCID 86672622, compound → HCID 86672622, compound

HRID 2369276Notes

Reaction equation

HRID 2369276 reaction equation
[CH3:1][C:2]([CH2:15][CH2:16][CH2:17][CH:18]([CH3:30])[CH2:19][CH2:20][CH2:21][CH:22]([CH3:29])[CH2:23][CH2:24][CH2:25][CH:26]([CH3:28])[CH3:27])=[CH:3][CH2:4][CH2:5][CH2:6][O:7][CH2:8][C@@H:9]([C@@H:11]([CH2:13][OH:14])[OH:12])[OH:10].[CH3:31][C:32]([CH2:45][CH2:46][CH2:47][CH:48]([CH3:60])[CH2:49][CH2:50][CH2:51][CH:52]([CH3:59])[CH2:53][CH2:54][CH2:55][CH:56]([CH3:58])[CH3:57])=[CH:33][CH2:34][CH2:35][CH2:36][O:37][C@H:38]([C@@H:41]([CH2:43][OH:44])[OH:42])[CH2:39][OH:40]>O>[CH3:1][C:2]([CH2:15][CH2:16][CH2:17][CH:18]([CH3:30])[CH2:19][CH2:20][CH2:21][CH:22]([CH3:29])[CH2:23][CH2:24][CH2:25][CH:26]([CH3:28])[CH3:27])=[CH:3][CH2:4][CH2:5][CH2:6][O:7][CH2:8][C@@H:9]([C@@H:11]([CH2:13][OH:14])[OH:12])[OH:10].[CH3:31][C:32]([CH2:45][CH2:46][CH2:47][CH:48]([CH3:60])[CH2:49][CH2:50][CH2:51][CH:52]([CH3:59])[CH2:53][CH2:54][CH2:55][CH:56]([CH3:58])[CH3:57])=[CH:33][CH2:34][CH2:35][CH2:36][O:37][C@H:38]([C@@H:41]([CH2:43][OH:44])[OH:42])[CH2:39][OH:40].[OH2:7]

Participants

5

Reactant 2

HCID 86672622HCID 86672622, compoundHCID 86672624HCID 86672624, compound

Product 2

HCID 86672622HCID 86672622, compoundHCID 86672623HCID 86672623, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

A mixture (1:1) of 1-O-(5,9,13,17-tetramethyloctadec-4-enyl)erythritol and 2-O-(5,9,13,17-tetramethyloctadec-4-enyl)erythritol and water were homogeneously mixed in accordance with the same procedure as in Example 13 to obtain a sample of the mixture (1:1) of 1-O-(5,9,13,17-tetramethyloctadec-4-enyl)erythritol and 2-O-(5,9,13,17-tetramethyloctadec-4-enyl)erythritol/water system. SAXS analysis of the sample of the mixture (1:1) of 1-O-(5,9,13,17-tetramethyloctadec-4-enyl)erythritol and 2-O-(5,9,13,17-tetramethyloctadec-4-enyl)erythritol/water system was performed in the same manner as in Example 13. As a result, at least 3 sharp scattering peaks were observed. The peak value ratio exhibited the following ratio peculiar to the reverse hexagonal liquid crystal: 1:√{square root over (3)}:2.

Sources & evidence

ORD record
ord-74179caa925c4d7d9fd5b578d0a098fc
Source dataset
uspto-grants-2014_04
Patent number
US08703922B2

Reaction notes

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