HuagongsheHuagongshe Chemistry Print Report · For research reference only
Tetrafluoroethylene → 4-(3,4-Dichlorophenyl)-2-(1,1,2,2-tetrafluoroethylthio)-5-(2-thienyl)-1H-imidazole
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Tetrafluoroethylene | HCID 8301 | — |
| Reactant | HCID 178527840 | HCID 178527840 | — |
| Product | 4-(3,4-Dichlorophenyl)-2-(1,1,2,2-tetrafluoroethylthio)-5-(2-thienyl)-1H-imidazole | HCID 21314992 | — |
Reaction Steps
4-(3,4-Dichlorophenyl)-5-(2-thienyl)-1H-2-imidazolethiol (30.0 g; 92 mmoles) was reacted with 15.0 g of tetrafluoroethylene as described in Example 4 E to give, after chromatography on Silicar CC No. 7 with chloroform, 19.1 g of 4-(3,4-dichlorophenyl)-2-(1,1,2,2-tetrafluoroethylthio)-5-(2-thienyl)-1H-imidazole, m.p. 178°-180° (recrystallized from toluene).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04159338 |
| Source dataset | uspto-grants-1979_06 |
| ORD ID | ord-f38521aec30f461d93b8edea20d116e7 |
| Source note | uspto-grants-1979_06 |