HCID 46947722, compound → HCID 46944760, compound

HRID 2370586Notes

Reaction equation

HRID 2370586 reaction equation
[CH3:1][C:2]1([CH3:42])[N:6]([CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12]CCCSCCCC(F)(F)C(F)(F)F)[C:5](=[O:27])[N:4]([C:28]2[CH:33]=[CH:32][C:31]([N+:34]([O-:36])=[O:35])=[C:30]([C:37]([F:40])([F:39])[F:38])[CH:29]=2)[C:3]1=[O:41].CS(OCCCCC[CH2:53][CH2:54][CH2:55][CH2:56][S:57][CH2:58][CH2:59][CH2:60][C:61]([F:67])([F:66])[C:62]([F:65])([F:64])[F:63])(=O)=O>>[CH3:42][C:2]1([CH3:1])[N:6]([CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:53][CH2:54][CH2:55][CH2:56][S:57][CH2:58][CH2:59][CH2:60][C:61]([F:67])([F:66])[C:62]([F:63])([F:65])[F:64])[C:5](=[O:27])[N:4]([C:28]2[CH:33]=[CH:32][C:31]([N+:34]([O-:36])=[O:35])=[C:30]([C:37]([F:38])([F:40])[F:39])[CH:29]=2)[C:3]1=[O:41]

Participants

3

Reactant 2

HCID 46947722HCID 46947722, compoundHCID 58899364HCID 58899364, compound

Product 1

HCID 46944760HCID 46944760, compoundYield 13%

Procedure

The experimental protocol used is the same as that described for the synthesis of the compound of Example 1, 10-[(4,4,5,5,5-pentafluoropentypthio]decyl methanesulphonate (prepared according to an experimental protocol similar to that described in WO 2005077968) replacing 9-[(4,4,5,5,5-pentafluoropentyl)-thio]nonyl methanesulphonate. The expected compound is obtained in the form of a pale yellow oil with a yield of 13% (125 mg).

Workup

  1. customprepared

Sources & evidence

ORD record
ord-13ded80b8fa44f4db270f8650a3c5e33
Source dataset
uspto-grants-2014_04
Patent number
US08710091B2

Reaction notes

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