HCID 46947722, compound → HCID 87134851, compound

HRID 2370606Notes

Reaction equation

[CH3:1][C:2]1([CH3:41])[N:6]([CH2:7][CH2:8][O:9][CH2:10][CH2:11][O:12][CH2:13][CH2:14][S:15][CH2:16][CH2:17][CH2:18][C:19]([F:25])([F:24])[C:20]([F:23])([F:22])[F:21])[C:5](=[O:26])[N:4]([C:27]2[CH:32]=[CH:31][C:30]([N+:33]([O-:35])=[O:34])=[C:29]([C:36]([F:39])([F:38])[F:37])[CH:28]=2)[C:3]1=[O:40].CC1(C)N(CCCCCCCCCSCCCC(F)(F)C(F)(F)F)C(=[O:68])N(C2C=CC([N+]([O-])=O)=C(C(F)(F)F)C=2)C1=O>>[CH3:1][C:2]1([CH3:41])[N:6]([CH2:7][CH2:8][O:9][CH2:10][CH2:11][O:12][CH2:13][CH2:14][S:15]([CH2:16][CH2:17][CH2:18][C:19]([F:24])([F:25])[C:20]([F:23])([F:22])[F:21])=[O:68])[C:5](=[O:26])[N:4]([C:27]2[CH:32]=[CH:31][C:30]([N+:33]([O-:35])=[O:34])=[C:29]([C:36]([F:38])([F:39])[F:37])[CH:28]=2)[C:3]1=[O:40]

Participants

Reactant 2

HCID 46947722HCID 46947722, compound

HCID 87134729HCID 87134729, compound

Product 1

HCID 87134851HCID 87134851, compoundYield 88%

Procedure

Compound 37 described below was synthesized according to a method similar to that described in Example 2 using compound 36 as starting reagent replacing 5,5-dimethyl-3-[4-nitro-3-(trifluoromethyl)phenyl]-1-{9-[(4,4,5,5,5-pentafluoropentyl)thio]nonyl}imidazolidine-2,4-dione. The expected compound is obtained in the form of a pale yellow oil with a yield of 88%.

Workup

custombelow was synthesized

Sources & evidence

ORD record: ord-9ed1957abe284d9f81cfd07d9622021c
Source dataset: uspto-grants-2014_04
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US08710091B2

Reaction notes

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