HuagongsheHuagongshe Chemistry Print Report · For research reference only
Diphosgene → 2-t-Butylimino-3-s-butyl-5-(p-methoxyphenyl)-tetrahydro-1,3,5-thiadiazin-4-one
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Diphosgene | HCID 10426 | — |
| Reactant | Sodium Hydroxide | HCID 14798 | — |
| Reactant | 1,3,5-Triazine, hexahydro-1,3,5-tris(4-methoxyphenyl)- | HCID 11058579 | — |
| Reactant | 1-s-Butyl-3-t-butylthiourea | HCID 12906296 | — |
| Product | 2-t-Butylimino-3-s-butyl-5-(p-methoxyphenyl)-tetrahydro-1,3,5-thiadiazin-4-one | HCID 12874402 | 76.9% |
Reaction Steps
Similarly, 2.7 g (0.0067 mole) of 1,3,5-tris(p-methoxyphenyl)-hexahydro-s-triazine, 2.0 g (0.01 mole) of trichloromethyl chloroformate, 3.8 g (0.02 mole) of 1-s-butyl-3-t-butylthiourea, and 16 ml of a 10% sodium hydroxide solution were used to obtain 1.8 g (26% yield) of 2-t-butylimino-3-s-butyl-5-(p-methoxyphenyl)-tetrahydro-1,3,5-thiadiazin-4-one (compound No. 355) of the formula: ##STR156## as white crystals melting at 63° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04159328 |
| Source dataset | uspto-grants-1979_06 |
| ORD ID | ord-d728dafd5aa347c0bfea81c7e2039390 |
| Source note | uspto-grants-1979_06 |