HRID2371624

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID12355864

1-(3-Bromopropoxy)-2-propylbenzene

C12H17BrO

结构：CCCc1c(O)ccc2c1OC(CCC(=O)OCC)(CCC(=O)OCC)CC2=O

HCID19756625

未命名化合物

PRODUCTS

生成物

结构：CCCc1ccccc1OCCCOc1ccc2c(c1CCC)OC(CCC(=O)OCC)(CCC(=O)OCC)CC2=O

HCID15157457

未命名化合物

收率 80.9%

PROCEDURE

实验过程

The title compound (471 mg) was prepared by the method of Example 18 except that the title product of Example 1 (406 mg) was used instead of the title product of Example 2, and the title product of Example 11 (308 mg) was used instead of benzyl bromide.

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-423ffc4dc1c1419d8eba24ea9f18ae2a
来源数据集: uspto-grants-1992_03
DOI: 10.6084/m9.figshare.5104873.v1
专利: US05093353
来源说明: uspto-grants-1992_03

反应 SMILES

[O:1]=[C:2]1[C:7]2[CH:8]=[CH:9][C:10]([OH:15])=[C:11]([CH2:12][CH2:13][CH3:14])[C:6]=2[O:5][C:4]([CH2:23][CH2:24][C:25]([O:27][CH2:28][CH3:29])=[O:26])([CH2:16][CH2:17][C:18]([O:20][CH2:21][CH3:22])=[O:19])[CH2:3]1.[CH2:30]([C:33]1[CH:43]=[CH:42][CH:41]=[CH:40][C:34]=1[O:35][CH2:36][CH2:37][CH2:38]Br)[CH2:31][CH3:32]>>[CH2:30]([C:33]1[CH:43]=[CH:42][CH:41]=[CH:40][C:34]=1[O:35][CH2:36][CH2:37][CH2:38][O:15][C:10]1[CH:9]=[CH:8][C:7]2[C:2](=[O:1])[CH2:3][C:4]([CH2:16][CH2:17][C:18]([O:20][CH2:21][CH3:22])=[O:19])([CH2:23][CH2:24][C:25]([O:27][CH2:28][CH3:29])=[O:26])[O:5][C:6]=2[C:11]=1[CH2:12][CH2:13][CH3:14])[CH2:31][CH3:32]