HRID2371625

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：CCCc1c(OCCCOc2ccc(Cl)cc2)ccc2c1OC(CCC(=O)OCC)(CCC(=O)OCC)CC2=O

HCID15157438

未命名化合物

结构：CCCc1ccccc1OCCCOc1ccc2c(c1CCC)OC(CCC(=O)OCC)(CCC(=O)OCC)CC2=O

HCID15157457

未命名化合物

PRODUCTS

生成物

结构：CCCc1ccccc1OCCCOc1ccc2c(c1CCC)OC(CCC(=O)O)(CCC(=O)O)CC2=O

HCID15157458

未命名化合物

PROCEDURE

实验过程

The title compound was prepared by the method of Example 22 substituting the title product of Example 40 (446 mg) for the title product of Example 21. Crystallization from ethyl acetate/hexane produced 252 mg as a solid, m.p. 163°-165° C.

WORKUP

后处理

customCrystallization from ethyl acetate/hexane
customproduced 252 mg as a solid, m.p. 163°-165° C.

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-c7014ad045334c4d8100a7010ea2fdda
来源数据集: uspto-grants-1992_03
DOI: 10.6084/m9.figshare.5104873.v1
专利: US05093353
来源说明: uspto-grants-1992_03

反应 SMILES

[CH2:1]([C:4]1[CH:42]=[CH:41][CH:40]=[CH:39][C:5]=1[O:6][CH2:7][CH2:8][CH2:9][O:10][C:11]1[CH:35]=[CH:34][C:14]2[C:15](=[O:33])[CH2:16][C:17]([CH2:26][CH2:27][C:28]([O:30]CC)=[O:29])([CH2:19][CH2:20][C:21]([O:23]CC)=[O:22])[O:18][C:13]=2[C:12]=1[CH2:36][CH2:37][CH3:38])[CH2:2][CH3:3].ClC1C=CC(OCCCOC2C=CC3C(=O)CC(CCC(OCC)=O)(CCC(OCC)=O)OC=3C=2CCC)=CC=1>>[CH2:1]([C:4]1[CH:42]=[CH:41][CH:40]=[CH:39][C:5]=1[O:6][CH2:7][CH2:8][CH2:9][O:10][C:11]1[CH:35]=[CH:34][C:14]2[C:15](=[O:33])[CH2:16][C:17]([CH2:26][CH2:27][C:28]([OH:30])=[O:29])([CH2:19][CH2:20][C:21]([OH:23])=[O:22])[O:18][C:13]=2[C:12]=1[CH2:36][CH2:37][CH3:38])[CH2:2][CH3:3]