Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Chlorine | HCID 24526 | — |
| Reactant | HCID 14460323 | HCID 14460323 | — |
| Solvent | Carbon Tetrachloride | HCID 5943 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Product | HCID 14460365 | HCID 14460365 | — |
Reaction Steps
286 μl of a solution containing 1.14 g/10 ml of chlorine in carbon tetrachloride are added to a solution of 110 mg of p-nitrobenzyl 5-azido-2-(4-tert-butylthio-2-oxo-1-azetidinyl)-4,4-dimethyl-3-oxopentanoate in 9 ml of methylene chloride at -60° C., and the mixture is subsequently stirred for 2 hours at -60° C. The reaction solution is evaporated in a rotary evaporator to give 119 mg of a yellow oil. IR spectrum in CH2Cl2 : 2930, 2860, 2105, 1780, 1755, 1720, 1610, 1530, 1350, 1190 cm-1.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US05096899 |
|---|
| Source dataset | uspto-grants-1992_03 |
|---|
| ORD ID | ord-9be39caf1f0a4ce38707179604fca439 |
|---|
| Source note | uspto-grants-1992_03 |
|---|
