HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 2371908Generated: October 27, 2026
Phosphorus oxychloride → HCID 67860849, compound
https://huagongshe.com/reaction/2371908
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Phosphorus oxychloride | HCID 24813 | — |
| Reactant | HCID 86745550 | HCID 86745550 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | HCID 67860849 | HCID 67860849 | 75.2% |
Reaction Steps
25.3 g (0.1 mol) of 2-carbamyl-5-nitro-7-methylbenzothiazolone-N-oxide are suspended in 150 ml of anhydrous toluene. 16.8 g (0.11 mol) of phosphorus oxychloride are added dropwise to this suspension, with stirring, at an internal temperature of 100° C. and the reaction mixture is heated under reflux for a further 4 hours and allowed to cool. 15.8 g (75 % of theory) of 5-nitro-7-methyl-benzothiazolone of melting point >250° C. are obtained.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US05096910 |
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| Source dataset | uspto-grants-1992_03 |
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| ORD ID | ord-7a43fe9ccd6349d88a6fa4d74ba946cc |
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| Source note | uspto-grants-1992_03 |
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