HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 2371994Generated: October 26, 2026
4-Chlorobenzoyl chloride → 6-(4-Chlorobenzoyl)-(6H)-dibenz[c,e][1,2]oxaphosphorin 6-oxide
https://huagongshe.com/reaction/2371994
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | 4-Chlorobenzoyl chloride | HCID 8501 | — |
| Reactant | 6-methoxy-(6H)-dibenz[c,e][1,2]-oxaphosphorin | HCID 11436148 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | 6-(4-Chlorobenzoyl)-(6H)-dibenz[c,e][1,2]oxaphosphorin 6-oxide | HCID 14366295 | — |
Reaction Steps
35 g (0.2 mol) of 4-chlorobenzoyl chloride were warmed to 90° to 100° C. under a nitrogen atmosphere. 46 g of 6-methoxy-(6H)-dibenz[c,e][1,2]oxaphosphorin were added dropwise while stirring. The internal temperature was then increased gradually to 130° C. When the reaction was complete, the mixture was digested with 50 ml of toluene. 60 g (85% of theory) of the abovementioned substance of melting point 125° to 131° C. were obtained.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| Patent number | US05096935 |
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| Source dataset | uspto-grants-1992_03 |
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| ORD ID | ord-54afb40b2c774d938deaff0f9337cb2a |
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| Source note | uspto-grants-1992_03 |
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