Sulfuric Acid → HCID 19905699, compound

HRID 2372004Notes

Reaction equation

[CH:1]1[C:6]([NH2:7])=[CH:5][CH:4]=[C:3]([NH2:8])[CH:2]=1.[NH2:9][C:10]1[CH:25]=[CH:24][C:13]([C:14]([NH:16][C:17]2[CH:22]=[CH:21][C:20]([NH2:23])=[CH:19][CH:18]=2)=[O:15])=[CH:12][CH:11]=1.S(=O)(=O)(O)O>>[CH:5]1[C:6]([NH2:7])=[CH:1][CH:2]=[C:3]([NH2:8])[CH:4]=1.[NH2:9][C:10]1[C:5]2[C:4](=[C:3]([NH2:8])[CH:2]=[CH:1][CH:6]=2)[CH:13]=[CH:12][CH:11]=1.[NH2:9][C:10]1[CH:25]=[CH:24][C:13]([C:14]([NH:16][C:17]2[CH:22]=[CH:21][C:20]([NH2:23])=[CH:19][CH:18]=2)=[O:15])=[CH:12][CH:11]=1

Participants

Reactant 2

HCID 1118Sulfuric Acid

HCID 19905701HCID 19905701, compound

Product 1

HCID 19905699HCID 19905699, compound

Procedure

U.S. Pat. No. 3,671,542 also describes that a copolyamide from p-phenylenediamine+4,4'-diaminobenzanilide (1:1) and terephthaloyl chloride+dibenzoyl chloride or 2,6-naphthaloyl chloride (1:1) becomes gel-like in amide solvents within a short period of time. The properties of the filaments (spun from sulfuric acid) are moderate. Only a 6-component polymer from (p-phenylenediamine+1,5-diaminonaphthalene+4,4'-diaminobenzanilide) and (terephthaloyl chloride+2,6-naphthaloyl dichloride+dibenzoyl chloride) gives a homogeneous solution in amide solvents. The properties of the filaments spun from sulfuric acid are moderate.

Sources & evidence

ORD record: ord-171cf889cae64fb19a6bcb76d2d88ac2
Source dataset: uspto-grants-1992_03
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05097015

Reaction notes

Loading…