HuagongsheHuagongshe Chemistry Print Report · For research reference only
Formaldehyde → 3-(3,5-Dimethoxy-4-hydroxybenzyl)-benzothiazole-2-thione
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Formaldehyde | HCID 712 | — |
| Reactant | 2,6-Dimethoxyphenol | HCID 7041 | — |
| Reactant | HCID 178418395 | HCID 178418395 | — |
| Catalyst | Dibutylamine | HCID 8148 | — |
| Solvent | Ethanol | HCID 702 | — |
| Product | 3-(3,5-Dimethoxy-4-hydroxybenzyl)-benzothiazole-2-thione | HCID 19807496 | 82% |
Reaction Steps
16.7 g of mercaptobenzothiazole, 3.0 g of paraformaldehyde, 15.4 g of 2,6-dimethoxyphenol and 1 g dibutylamine are heated at 110°, with rapid stirring, for 2 hours. 50 ml of ethanol are added and the mixture cooled to 10° thereby obtaining 27.3 g of 3-(3,5-dimethoxy-4-hydroxybenzyl)-benzothiazole-2-thione (compound No. 8) melting at 141°-142°.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05097039 |
| Source dataset | uspto-grants-1992_03 |
| ORD ID | ord-09095e94af8c41e5be70da12db63967a |
| Source note | uspto-grants-1992_03 |